1. Preheat your oven to 450° F. This high heat is essential for achieving perfectly roasted chicken and broccoli. Line a baking sheet with parchment paper or rub it with a bit of oil to prevent sticking.
2. Take the sheet pan and mix the chicken, orange zest, and black pepper together in a bowl. This combination already smells amazing! Add the flour and toss again to ensure the chicken is well-coated. The flour will help create a beautiful crust as it bakes.
3. Drizzle 2 tablespoons of extra virgin olive oil over the chicken, tossing to coat thoroughly. Now, arrange the chicken on one side of the baking sheet while placing the broccoli florets on the other side. Toss the broccoli with olive oil, salt, and pepper to enhance its flavor.
4. Slide the baking sheet into the oven and bake for 15 to 20 minutes. Keep an eye on the chicken; you want it cooked through and slightly golden.
5. While the chicken and broccoli are roasting, it’s time to make the sauce. In a saucepan, combine the fresh orange juice, remaining orange zest, tamari, rice vinegar, honey, garlic, grated ginger, and chili paste. Set it over medium heat and bring it to a gentle boil for about 3 to 4 minutes. You’ll see it start to bubble and thicken slightly.
6. After the chicken and broccoli have baked, remove the baking sheet from the oven. Set the broccoli aside and pour the orange sauce over the chicken. Toss to coat the chicken in the glossy sauce. It’s going to look so appetizing!
7. Return the baking sheet to the oven for another 5 minutes. This final baking allows the sauce to caramelize and stick to the chicken, enhancing the flavors.
8. When ready to serve, plate the chicken and broccoli together, garnishing with sliced green onions and a sprinkle of sesame seeds. You can also serve it over rice for a delightful meal.